新型"超级冰"强度提升10倍,接近混凝土强度
New 'super ice' 10 times stronger, bringing it close to the strength of concrete

原始链接: https://www.sciencealert.com/a-new-super-ice-is-10-times-stronger-bringing-it-close-to-the-strength-of-concrete

以色列研究人员开发了一种名为BioPykrete的革命性材料,其灵感来自二战时期的Pykrete。通过将冰与植物源纤维素纳米晶体及定制蛋白质粘合剂结合,他们创造出一种比普通冰强10倍、断裂前吸收能量多70倍的复合材料。与传统冰不同,它逐渐变形而非碎裂。该材料使用纤维素纳米晶体和一种充当分子胶水的蛋白质(CBM3a-AFPIII),在纳米尺度上结合各组分。它旨在用于北极、南极等偏远寒冷地区的建设,提供一种低碳、可生物降解的混凝土与钢铁替代品。发表于《Colloids and Surfaces B: Biointerfaces》的这项概念验证研究强调了极端环境下可持续生物材料。虽然前景广阔,但长期耐久性仍需进一步研究。研究团队认为,优化冷冻方法和蛋白质变体可进一步提高强度,可能将应用扩展到包装和结构工程。

一个 Hacker News 帖子讨论了 ScienceAlert 上关于一种新型“超级冰”的文章,据说其强度是普通冰的 10 倍,接近混凝土强度,由冰和植物基纤维素制成。评论者将其与派克里特(pykrete)比较,指出纤维可以增强冰的强度。提出的用途包括冰路、偏远北极/南极建设、临时脚手架、包装以及太空或行星结构。有人质疑其融化和实用性;其他人则指出添加剂可以减缓融化并提高耐久性。该材料可能可生物降解且低碳,但气候变化可能限制寒冷地区应用。帖子还包含关于冰子弹、滑冰场冰的特性、《Seveneves》和冰九的题外话。总体而言,该技术被认为是有前景但利基的,最受关注的是寒冷环境工程和可能的太空建设。
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原文

During the Second World War, the British Royal Navy experimented with the idea of using ice reinforced with wood pulp to build an aircraft carrier.

The composite material, known as Pykrete, was apparently as strong as concrete, as long as it could be kept frozen.

The ship would've effectively been a floating, custom-made, strengthened iceberg for planes to take off from and land on – but with rising costs and better options becoming available, the project was eventually abandoned.

Now researchers led by a team from the Hebrew University of Jerusalem in Israel have extended that idea from the 1940s to create what they're calling BioPykrete.

By adding plant-based crystals and a bespoke protein to ice, they've created something that's 10 times stronger than regular ice and able to absorb 70 times more energy before breaking.

A study of the new material has been published in Colloids and Surfaces B: Biointerfaces, and the team behind it hopes that it may one day be used as a building material.

Super ice
A sample of the new ice. (Chen Adar)

"We wanted to go beyond simply mixing fibers into ice and instead control how the different materials connect at the molecular level," says biochemist Ido Braslavsky, from the Hebrew University of Jerusalem.

"The result changes not only how strong the ice is, but also how it breaks. Instead of suddenly shattering, it can absorb much more energy and deform gradually."

The intended application isn't for aircraft carriers this time, but rather for construction projects in remote, cold areas where conventional building methods aren't easy to apply – like the Arctic and Antarctic.

With no concrete or steel required, and with ice and plant-based cellulose as the main ingredients, this could be a building material with a low carbon footprint that's also biodegradable.

"While the construction industry is a cornerstone of the global economy, it remains one of the most significant environmental polluters, responsible for substantial carbon emissions and massive resource depletion," write the researchers in their published paper.

"Biotechnology offers a transformative pathway to mitigate this impact by developing novel, sustainable biomaterials."

It's going to be a while before BioPykrete can be used as a construction material, however. This study was a small-scale proof-of-concept test, and further research will be needed to look at how BioPykrete stands up over long periods and under changing conditions.

Instead of wood pulp's larger, disordered fibers, the researchers used cellulose nanocrystals here.

Cellulose is the main structural material in plants, and in nanocrystal form, it can act as a microscopic strengthening agent for other materials, including ice – essentially stopping cracks from spreading easily.

The protein used here was called CBM3a-AFPIII, a combination of an antifreeze protein (AFP) and a carbohydrate-binding module (CBM). Its job was to act like glue, keeping the cellulose nanocrystals and ice bonded together.

Protein structure
Scanning electron microscope images of freeze-dried samples reveal the network formed by tiny cellulose crystals. The top row shows the material magnified 40 times, and the bottom row 90 times. (Yulia Baron and Dr. Liat Bahari)

It's a clever approach, and the researchers think that by tweaking their ingredients and methods, they might be able to improve their 'super ice' even further.

"Optimizing solidification kinetics and freezing protocols, alongside developing diverse AFP-CBM variants, could yield even higher-strength composites," write the researchers.

Besides further tests of the durability of the material, the researchers are also keen to take a closer look at how cracks propagate through BioPykrete, to confirm that the underlying strengthening mechanisms are what they think they are.

Further down the line, this approach could open up a whole new landscape for materials used in packaging, construction, and more: Using a custom protein to bring two unlikely compounds (ice and cellulose) together.

"By bridging the gap between recombinant protein design and structural engineering, we have developed a high-performance material specifically engineered for the rigors of the world's most extreme environments," write the researchers.

The research has been published in Colloids and Surfaces B: Biointerfaces.

This article was fact-checked by Rebecca Dyer and edited by Rebecca Dyer. While we pride ourselves on our process, we are only human. If you spot a mistake, please let us know.

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